Effect of pH in the Pd-catalyzed oxidation of D-glucose to D-gluconic acid
ArticleAbbadi, A., Makkee, M., Visscher, W., Veen, van, J.A.R. & van Bekkum, H. (1993). Effect of pH in the Pd-catalyzed oxidation of D-glucose to D-gluconic acid. Journal of Carbohydrate Chemistry, 12(4-5), 573-587. In Scopus Cited 30 times.
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The pH effect on the Pd-catalyzed oxidn. of glucose to gluconic acid was studied. The oxidn. reactions were performed in the pH range 2 to 9 in a batch reactor using Pd/C or Pd black as the catalysts and monitoring the behavior of the catalyst during the oxidn. reaction. The Pd-glucose system was also studied by cyclic voltammetry. It is concluded that gluconic acid in its free form reversibly inhibits the oxidn. process in acidic media.