Rob Verpaalen receives the DPI Thesis Award for his Phd Work on making commodity polymers stimuli-responsive!

Imagine that products have a longer shelf life because of smart packaging, that plastic robots are driven by their environment and that clothing adapts while being worn. In short; that you can make plastic smart so that the material reacts to its environment, for example by adjusting humidity, temperature or light. For his PhD research Rob Verpaalen looked at how you can produce bulk plastics without radically altering the current industrial processing processes. He obtained his PhD on 22 September at the Department of Chemical Engineering and Chemistry.

Plastics are produced cheaply and in bulk quantities, think of packaging materials and textiles. If these conventional static plastics can be made responsive and therefore 'smart', this will lead to new materials and applications. The current industrial processing process is based on the materials polyethylene, polyamide 6 (PA6, Nylon) and polyethylene terephthalate (PET). To make these materials responsive, they are sprayed with coatings or mixed with additives.

Verpaalen investigated the influence of temperature and humidity incentives on the shape change in Nylon. He showed that bending only occurs thermally at elevated humidity. This shows that shape change can be programmed. In order to convert this simple bending to a more advanced shape change, Verpaalen used a special coating with a spiral staircase structure. By varying the coating thickness, the material no longer bends, but instead forms a curl. 

CHANGING SHAPE BY LIGHT

Verpaalen then combined a thermoplastic PET substrate with a responsive coating. This created a reprogrammable, light-sensitive and shape-changing plastic. These so-called bilayer actuators react quickly, reversibly and locally under the influence of ultraviolet and visible light. The new plastic even shows several different shape changes in one actuator.

Light sensitive actuators are also developed by adding unique light sensitive azobenzene molecules (with PE side groups) to ultra high molecular weight polyethylene. The highly oriented plastic films then generate exceptionally high voltages, similar to metallic actuators, under the influence of ultraviolet and visible light.

Title of PhD thesis: Stimuli-Responsive Commodity Polymers. Supervisors: A.P.H.J. Schenning, M.G. Debije, C.W.M. Bastiaansen, Laboratory of Stimuli-responsive Functional Materials & Devices (SFD), Eindhoven University of Technology. T.A.P. Engels, Materials Technology Institute (Polymer Technology), Eindhoven University of Technology.